What are the connections between spectral expansion and differential operator?

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For instance, for a nice function $f$ on the unit circle, we have its Fourier expansion, $$f(x)=\sum_n \hat{f}(n) e^{inx},$$ where the exponentials are eigenfunctions for differential operator $d/dx.$

I feel confunsed about the connection between the differential operator and spectral expansion of an arbitrary function. (In the example above, the connection between $d/dx$ and the Fourier expansion.) Why do people often say a differential operator (e.g., Laplacian) has a spectral expansion?

Thank you!