I'm hoping to construct a physical model of a 4D cube. However, I'm struggling to work out the proper size ratio between the inner and outer cubes. From the graphics I've seen, the inner cube seems about 1/3 the size of the outer, but I haven't been able to find any documentation for that. How would you go about working that out?
Thanks for your time.

Go for what looks best. There is no mathematical reason for any particular size.
A 3D model of a 4D cube is a projection. It is like perspective in a photo or painting. Things that are further away are smaller, but depending on the distance of the observer, the relative sizes of two things in the painting at different distances can vary. Similarly, the "inner" cube of a classic hypercube projection is further away than the outer cube along the unavailable fourth dimension, and hence is depicted smaller. The size difference depends on how far away you as an observer are along that same dimension, so could be anything.