Is there any rigorous definition of "orientation" of a platonic solid?
Lots of books mention that the whole group of symmetries of platonic solids consists of rotations composed with reflections, but I'm not sure how we know that the reflections produce only two possible orientations. Furthermore, rotations are said to preserve orientation whereas reflections are said to "invert" the orientation.
Firstly, by "reflection" I assume they mean reflection about a plane?
Secondly, how do we know that there are only 2 possible "orientations" of a platonic solid and not any more or any less than that?
Some supporting visuals/diagrams would be great as well!


Rotations of platonic solids are subgroups of rotations in general. So let's talk why rotations in general preserve orientation. If you take three base vectors $\hat\imath$, $\hat\jmath$, $\hat k$, then the mixed product $(\hat\imath\times\hat\jmath, \hat k)=1 > 0$. If a transformation keeps this product positive, than we say that the transformation preserves orientation. For example, if rotation around $(1,1,1)$ by 120° cyclically swaps base vectors, so we end up with product $$(\hat\imath_1\times\hat\jmath_1, \hat k_1)=(\hat\jmath\times\hat k, \hat\imath)=1>0$$ and we say that this rotation preserves orientation. If instead, we take a reflection around plane $xy$, then $$(\hat\imath_1\times\hat\jmath_1, \hat k_1)=(\hat\imath\times\hat\jmath, -\hat k)=-1 < 0$$ and we say that reflection switches orientation.
One can show that distance preserving transformations (rotations and reflections) can make this mixed product either $1$ or $-1$. So there are only two possible orientations.