The focus of propositional logic is said to be argument schemas that lead to valid conclusions, and not with the contents of the arguments themselves. This implies that an argument can consist of empirically false premises (i.e. factually false) but can still lead to a valid conclusion. For example consider the following valid argument:
All cups are green.
Socrates is a cup.
Therefore, Socrates is green.
Given then that we are not concerned with 'empirical truth' of statements in propositional logic, what do the 'truth values' assigned to statements in a truth table represent/indicate? What is meant be 'truth' in propositional logic?
Please could you ensure any answers are stated in simple terms as my understanding is minimal.

Every row in a truth-table represents a type of 'world' or 'situation'. E.g. in our world, it is not true that all cups are green, but we can also think of worlds where all cups are green. Or, in terms of situations: there are situations where all cups are green (maybe someone notices that all the cups on the table are green and, restricing our 'domain' to just those cups, it would indeed be true that 'all cups are green'. But obviously, there are other scenarios or situations where not all cups are green.
This is exactly why this kind of statement is said to be a contingency: the truth-value of the statement is dependent on what the world/situation is like.
Also, in this sense, you are exactly right that logic does not care whether some statement is actually true (i.e. true in our world) or not: our world is just one of many possible worlds, and in logic we give no preference of one over the other. Logicians can contemplate worlds where pigs can fly just as easily as one where they don't.
A truth-table systematically exhausts all possible types of worlds relevant to the statements at hand. The truth-values in the 'reference colums' indicate what kind of world we are dealing with, e.g. if statements $P$ and $Q$ are set to True, then that tells us we are dealing with a kind of world where they are oth True. And, once we have set those values, we can work out the truth-conditions for the statement we are interested in ... and hopefully learn something from that (e.g. whether some argument is logically valid, or whether two statements are equivalent or ...)