I. Logarithmic integral
The logarithmic integral $\rm{li}(z)$ has a unique positive zero at $z \approx 1.451363$ called the Ramanujan-Soldner constant.
II. Cosine integral
The cosine integral $\rm{Ci}(x)$, on the other hand, has infinitely many zeros,
The smallest is nameless and is $x_0 \approx 0.61650548$. For the next zeros, I notice they can be approximated by rational multiples of $\pi$,
$$\begin{array}{|c|c|c|} \hline n&x_n&n\pi\\ \hline 1&3.38&3.14\\ 2&6.42&6.28\\ 3&9.52&9.42\\ 4&12.64&12.56\\ \hline \end{array}$$
III. Sine integral
The sine integral $\rm{Si}(y)$ equated to $\frac{\pi}2\approx 1.57$ also has infinitely many zeros.
The smallest is again nameless and is $y_0 \approx 1.92644766$. The next zeros are,
$$\begin{array}{|c|c|c|} \hline n&y_n&(2n+1)\tfrac{\pi}2\\ \hline 1&4.89&4.71\\ 2&7.97&7.85\\ 3&11.08&10.99\\ 4&14.20&14.13\\ \hline \end{array}$$
IV. Questions
- Do the expressions $x_n - n\pi$ and $y_n - (2n+1)\frac{\pi}2$ converge to some non-zero constant?
- Are there better approximations to the roots $x_n$ and $y_n$?



If you look here, you will see that the zeros are given by $$a+\frac{1}{a}-\frac{16}{3\, a^3}+\frac{1673}{15\, a^5}-\frac{507746}{105 \, a^7}+O\left(\frac{1}{a^9}\right)$$ where $a=k \pi$ for the cosine integral and $a=\left(k+\frac 12\right)\pi$ for the sine integral.
If you want a more compact form, you could use $$a+\frac{240 a^2+3739}{a(240 a^2+5019)}$$ I built it from the above.