Equation 7 of "Particle Shape Factors and Their Use in Image Analysis–Part 1: Theory" (PDF) defines circularity as
$$\text{circularity} = \sqrt{\frac{4\pi\cdot\text{area}}{\text{perimeter}^2}}$$
Which type of triangle has the largest circularity value, and how does one prove it?

Since the circularity measure of similar triangle is the same, we may normalize the triangles to have a fixed perimeter, say $1$, and then the problem is simply to find the triangle of maximum area and given perimeter.
It is well-known that the answer is an equilateral triangle. This is easy to show using Heron's formula and Lagrange multipliers, as is done here.