A. Döring says in the book "Deep Beauty Understanding the Quantum World Through Mathematical Innovation", that, for the Gelfand spectrum defined as:
Definition: A Gelfand spectrum $\Sigma_V$ consists of the positive linear functionals from a abelian subalgebra $V$ of a encompassing von Neumann algebra $\mathfrak{M}$, such that they have norm $1$ and are algebra homomorphisms from $V$ to $\mathbb{C}$.
He then says that for any $\lambda \in \Sigma_V$, it can be shown that for any self-adjoint $A \in V_{sa}$, the following relation holds: $$\lambda(A) \in \sigma(A)$$ where $\sigma(A) \subset \mathbb{R}$ is the usual spectrum of $A$.
How does one prove this? Is it a consequence of the Gelfand–Mazur theorem? In which case, is this then implied because $\lambda$ sends the self-adjoint $A$ to an arbitrary complex number and, by the Gelfand–Mazur theorem(?), the entirety of $\mathbb{C}$ is isomorphic to $\sigma(A)$, making that arbitrary complex number be somewhere in $\sigma(A)$?
(Not sure if that is what the Gelfand–Mazur theorem implies, I kinda stumbled upon it when looking for the reason why $\lambda(A) \in \sigma(A)$, and from a surface reading of the statement of the theorem, he seems to be exactly what needs to be used to prove that type of relation.).
It is just a direct observation: $$ \lambda(A-\lambda(A)1)=\lambda(A)-\lambda(A)=0, $$ so $A-\lambda(A)\in\ker\lambda$. Because $\lambda$ is not zero, one easily check that $\lambda(1)$ has to be a projection; and the only nonzero projection in $\mathbb C$ is $1$. So $\lambda$ is unital. If $A-\lambda(A)1$ were invertible, then its image would have to be nonzero by the multiplicativity of $\lambda$. Hence $A-\lambda(A)1$ is not invertible, and $\lambda(A)\in\sigma(A)$.
With a bit more work one can show that on any unital abelian Banach algebra you have $$ \sigma(A)=\{\lambda(A):\ \lambda:V\to\mathbb C\ \text{ nonzero homomorphism}\}. $$