Please refer to the following image for clarity.
In this diagram I must find AC ( which is$\sqrt21$) in order to find the radius of the circle. I know that the radius can be found by dividing the diameter by $2$, and I know that the diameter is equal to AC/sin(60). My question is, why is this true? Why is the diameter equal to this?


Simple construction. AE is the diameter through circum-center $O$. $\angle ACE= 90^{\circ},$ subtended in semi-circle $ADCE$. Subtended angles on$B$ side of $AC$ are always the same in magnitude.
So, the hypotenuse or diameter
$$ AE =\frac{AC}{\sin 60^{\circ}}$$
Repeat this thrice, once each for three of the vertices A,B or C and you have already derived the Law of Sines:
$$ \frac{a}{\sin A} = \frac{b}{\sin B}=\frac{c}{\sin C}= AE $$