A differential $n$-form is defined as a totally antisymmetric $(0,n)$-tensor field on the surface of a manifold. Why must they be antisymmetric?
I understand this has something to do with asking which kinds of tensors can you define a derivative without any more structure.
EDIT: I can't help but give more context to this.
The ultimate goal is to find a way to define an integral on an manifold without using any geometric structure such as a Riemannian metric. Why anyone would think this should be possible is beyond me. But now that we know the answer, we can concoct a story like the following.
If you're going to integrate something over a manifold, you'd better start with the simplest possible situation. The usual way to start is to chop a 2d region into rectangles and do a weighted sum of areas of the rectangles. But that construction is clearly coordinate dependent.
So the initial focus is on defining the area of a rectangle in an abstract vector space $V$ (not $\mathbb{R}^2$ because that implies coordinates). But in $V$ there are no rectangles, only parallelograms.
We therefore want to show that the area of the parallelogram spanned by two vectors in $\mathbb{R}^2$ can be defined in a purely abstract way that uses only the vector space structure and no other assumptions on $V$. To do this, the idea is to use what we know about the area of a parallelogram in Euclidean space but without relying on any formula for it.
Let $A(v,w)$ be the area of the parallelogram spanned by $v, w \in V$. Note that the area function is really well defined only up to a scalar factor, but we'll just work with one of them. We want to derive the properties of $A$ using, say, only pictures and basic geometry.
For convenience, let's draw $v$ horizontally and observe that any vector not parallel to $v$ points either upward or downward.
The picture
shows that if both vectors $w_1, w_2$ both point upward, then $$A(v,w_1+w_2) = A(v,w_1) + A(v,w_2).$$ Using the fact that the area of a parallelogram is base times height, it's easy to see that, if $c > 0$, then $$ A(v,cw) = cA(v,w). $$ This is tantalizingly close to a linear function of $w$. In fact, there is a unique extension of $A$ to be a linear function of $w$, but then the area of the parallelogram is $|A(v,w)|$. You could start with this and define things that can be integrated over a manifold. This leads to the definition of a density. The argument below shows that $A$ still has to be an exterior $2$-tensor, so antisymmetry is always there but you can hide it using the absolute value.
The brilliant insight someone came up with is that it makes sense to omit the absolute value and call $A(v,w)$ the signed area of the parallelogram. Linearity with respect to $w$ implies that the area of the parallelogram is positive if $w$ points upward and negative if it points downward. Antisymmetry now appears, because if $w$ points upward relative to $v$, then $v$ points downward relative to $w$. Therefore $$A(w,v) = - A(v,w)$$ And of course, this also implies that $A(v,w)$ is a linear function of $v$. And therefore, $A$ is an antisymmetric $2$-tensor.
Notice that we never used coordinates, length, or angle in deriving this conclusion. So $A$ is well-defined, up to a nonzero constant factor, with respect to any linear transformation of $V$. Orientation now appears because the constant factor has a sign.
So why use signed area instead of area? The fact that $A$ is algebraically way easier to work with than $|A|$ is strong motivation. However, the deciding factor is Stokes' theorem. At this point, I do use coordinates and consider a rectangle in $\mathbb{R}^2$. The goal is to find a 2d fundamental theorem of calculus. If ultimately you want to make this coordinate independent, then the only possible integral around the boundary is a line integral. If you write the formula for a line integral (of a $1$-form) and apply the 1d fundamental theorem of calculus, the resulting double integral is easily seen to be an antisymmetric 2-tensor. In this one calculation, you see how to define the exterior derivative of a $1$-form and prove Stoke's theorem on a rectangle.
Moreover, if you omit the absolutely value, then you can glue rectangles together and extend Stokes' theorem to manifolds with boundary. That's not possible with densities.
From here, it is straightforward to develop the calculus of differential forms.