$x\otimes 1\neq 1\otimes x$

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In Bourbaki, Algèbre 5, section 5, one has $A$ and $B$ two $K$-algebras in an extension $\Omega$ of $K$. It is said that if the morphism $A\otimes_K B\to \Omega$ is injective then $A\cap B=K$. I see the reason: if not there would exist $x\in A\cap B\setminus K$ so that $x\otimes 1=1\otimes x$ which is false.

But why $1\otimes x\neq x\otimes 1$ for $x\notin K$?

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For any $K$-module $T$ there is a canonical isomorphism $$ \operatorname{Hom}_K(A\otimes B,T)\simeq\operatorname{Bil}_K(A\times B,T). $$ Thus in order to prove that $x\otimes1\neq1\otimes x$ it is enough to produce a bilinear map $\phi:A\times B\rightarrow T$ such that $\phi(x,1)\neq\phi(1,x)$.

Take $T=K$ and let $\lambda\in A^\ast$, $\mu\in B^\ast$ such that $\lambda(x)=0$, $\lambda(1)=1$ and $\mu(x)=1$. Then $\phi(a,b)=\lambda(a)\mu(b)$ works.

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I hope you know that if $\{v_i\}$ is a basis of $V$ and $\{w_j\}$ is a basis of $W$, then $\{v_i\otimes w_j\}$ is a basis of $V\otimes W$. Now since $x\notin K$, we can extend $\{1,x\}$ to a basis of $A$ and $B$, respectively. Now as a corollary of the above claim you have in particular that $1\otimes x$ and $x\otimes 1$ are linearly independent. In particular they are not equal.