Is it possible for every $N=p^n, n\in\mathbb{N}^*, p$ prime, to define an operation $\star:\mathbb{Z}_N\times\mathbb{Z}_N\to\mathbb{Z}_N$ such that the structure:
$$(\mathbb{Z}_N, +, \star)$$ will be a field, where the adition is the usual one in the group $\mathbb{Z}_N$?
edit: Taking into account the comments on this answer, I have to add one point: I am assuming in my answer that $1$ is the multiplicative neutral element for the multiplication $\star$. That doesn't need to be true in general. Given the multiplication $\star$ with neutral element $a$, we first show that $1$ is a unit.
For that, use that $$a = a\star a = (\sum_{i=1}^a 1)^2 = \sum_{i=1}^{a^2} 1^2 = 1 \star \sum_{i=1}^{a^2} 1.$$ Therefore, let $1^{-1}$ be the inverse of $1$ with respect to $\star$. Then we can define a new multiplication $\star'$ by $$x \star' y := x \star y \star 1^{-1}.$$ This will give us a multiplication with $1$ as neutral element and by mapping $1 \mapsto a$, both rings are isomorphic (or you get a contradiction with the axioms, e.g. in the case $gcd(a,N) > 1$).
Therefore, we can w.l.o.g. assume that the neutral element is indeed $1$.
Sorry that I forgot about that before, it is not that trivial to get that we can assume $1$ as neutral element, but it is very easy to just assume it without thinking enough about it.
The comments are most likely due to the fact that all finite fields are known and classified, and from that we can easily see that $\mathbb{Z}_N$ with its natural addition will never be one of them, unless $N = p$ is a prime of course (but there we already know which multiplication to take).
As I think that you didn't study this classification yet, let's look for a more elemental proof that this does not work:
Assume that $N$ is not a prime. Then there are numbers $1 < a,b < N$ such that $N = ab$. When we multiply these resp. their residues in $\mathbb{Z}_N$, we can use the distributive law to look at $$a \star b = (\sum_{i=1}^a 1)\star (\sum_{i=1}^b 1) = \sum_{i=1}^{ab} 1\star 1.$$ Of course you might want to add further steps here, but be sure to only use the axioms for a multiplication, e.g. distributive law, associative law, etc.
Now in the last sum, we sum $N = ab$ ones, so this product needs to be equal to $N$ - no matter how exactly $\star$ was defined. But that is a problem (why?).
Note that in this way, you can even show that the classical multiplication is the only one that makes $\mathbb{Z}_N$ with its normal addition into a ring.