Let $G : \mathcal{D} \rightarrow \mathcal{C}$ be a functor. Suppose that for each object $X \in \mathcal{C}$, there exists a universal morphism $(F_X, \eta_X)$ from $X$ to $G$. The theory of adjoint functors tells us that we can construct a unique functor $F : \mathcal{C} \rightarrow \mathcal{D}$ such that $F(X) = F_X$ and $\eta = (\eta_X)_X$ is a natural transformation. Indeed, given $f : X \rightarrow Y$, we can use universality of $(F_X, \eta_X)$ and define $F(f)$ to be the unique $h : F_X \rightarrow F_Y$ such that $G(h) \circ \eta_X = \eta_Y \circ f$. This $F$ will be a left adjoint of $G$.
However, it seems plausible to construct another functor $F'$ such that $F'(X)=F_X$, but which is defined differently on arrows, in a way so that $F'$ is no longer a left adjoint of $G$. To get around the above uniqueness condition, it would have to be done so that $\eta$ is no longer a natural transformation. Is this possible? Are there any simple examples (e.g. where $G : Grp \rightarrow Set$ is the forgetful functor and $F : Set \rightarrow Grp$ is the free functor)?
EDIT: I realized my question is equivalent to the following. Let $F,F' : \mathcal{C} \rightarrow \mathcal{D}$ and $G : \mathcal{D} \rightarrow \mathcal{C}$ be functors. Suppose that $F$ and $F'$ agree on objects (i.e. $F(X)=F'(X)$ for each object $X \in \mathcal{C}$). If $F$ is a left adjoint of $G$, does it follow that $F'$ is also a left adjoint of $G$?
In the special case $F = G = \mathrm{id}_{\mathcal{C}}$, this becomes: If $F ' : \mathcal{C} \to \mathcal{C}$ is a functor which is the identity on objects, is $F' \cong \mathrm{id}_{\mathcal{C}}$? This would imply in particular that $F'$ is fully faithful. But this already fails for one-object categories, i.e. monoids. Any non-bijective monoid homomorphism $ M \to M$ is a counterexample.