Let $\alpha : \mathbb{Z}_2 \rightarrow Aut(\mathbb{Z}_3) \cong \mathbb{Z}_2$ be the homomorphism given by $\alpha_{\bar{1}}(\bar{1}) = \bar{2} \in \mathbb{Z}_3$. Write down the Cayley table for $G=\mathbb{Z}_3 \rtimes _\alpha \mathbb{Z}_2$.
So letting $\mathbb{Z}_3 = \{e,a,a^2\}$ and $\mathbb{Z}_2 = \{e,b\}$, I came up with the table:
\begin{array}{|c|c|c|} \hline *& e & a & a^2 \\ \hline e & (e,e) & (e, a) & (e, a^2)\\ \hline b & (b,e) & (b,a^2) & (b,a)\\ \hline \end{array}
I'm not sure this is right, however. I don't think I properly used the expanded definition of $\alpha$ to generate this table. What's the proper Cayley table for $G$?
I can't make tables, but I can tell you what to do. You have omitted many elements! $|G| = 2\cdot 3 = 6$ so you should have a six-by-six table. The elements of $G$ are pairs $\{\bar{0}, \bar{1}, \bar{2}\}\times\{\bar{0}, \bar{1}\}$ and the "multiplication" (funny-looking addition, in this case) is given by $$(a, b) + (a', b') = (a+\alpha_b(a'), b+b').$$ Can you work it out from here?
I also suggest not redefining $\mathbb{Z}_3 = \{e, a, a^2\}$ and $\mathbb{Z}_2 = \{e, b\}$ when you are already given their descriptions, unless you also translate the definition of $\alpha$ into this new notation.