Powersets can be seen as complete atomic boolean algebras.
Is it possible to characterize complete atomic boolean algebras (CABA) among complete partial orders (CPO)?
For example, it is possible to characterize complete Heyting Algebras as complete posets where $$a \wedge \bigvee a_i = \bigvee a \wedge a_i.$$
In this sense a complete boolen algebra is just a complete partial order with an exactness property, the infinitary distributivity law.
My guess, in fact my hope, is that CABAs correspond to complete atomic regular posets. By regular I mean that the poset is a regular category.
As indicated in this nlab page,
The definition of atom and atomic is a bit different from the one expected by lattice theorists. Traslating from mine terminology to theirs, atomic means that there is a join-dense subset of completely join-irreducible elements.