I know that:
$$\sum_{k=1}^n\arctan(2k^2)=\frac{\pi n}{2}-\frac{1}{2}\arctan(\frac{2n(n+1)}{2n+1})$$
Can a similar closed form expressions be given for $\sum_{k=1}^n \arctan(k^2)$?
I was able to simplify it to:
$$\sum_{k=1}^n\arctan(k^2)=\frac{\pi n}{2}-\arctan(\frac{2n(n+1)}{2n+1})+\sum_{k=1}^n\arctan(\frac{1}{4k^6+3k^2})$$
But I can't simplify the sum on the right hand side.
The sequence $\tan\left( \sum_{k=1}^n \arctan(k^2)\right)$ starts (for $n = 1$ to $15$) $$1,-\frac53,{\frac {11}{24}},-{\frac {395}{152}},{\frac {3405}{10027}},-{ \frac {364377}{112553}},{\frac {2575360}{8983513}},-{\frac {33971776}{ 9167031}},{\frac {708557735}{2760880887}},-{\frac {276796646435}{ 68094892613}},{\frac {3981342679869}{16780244555624}},-{\frac { 2420336558689725}{556533101345512}},{\frac {91633757568701803}{ 409593411519909037}},-{\frac {1960291278426118855}{428063977364527911} },{\frac {2775120694958607680}{12985105930095331479}}$$
I don't see any closed form. The numerators and denominators don't seem to be in the OEIS, nor does Maple's gfun come up with anything. There certainly isn't anything "similar" to what you have with $2k^2$.