Suppose we have an irreducible polynomial $p(x)$ of degree $n$ in $F[x]$, where $F$ is a field. Let $K$ be the field $F[x] / (p(x))$.
We can consider the extension of $K$ over $F$ as a vector space over $F$. Evidently, this field has a basis and it is given by $\{1, \theta, \dots , \theta^{n-1}\}$, where $\theta = x \pmod{p(x)} \in K$.
I'm a bit confused about this definition of $\theta$. Maybe it's just because I'm a bit uncomfortable reducing polynomials modulo a prime polynomial ideal, but how exactly can we use this definition to deduce that $\theta = i$ when considering $\mathbb{R}[x]/(x^{2} + 1)$? Or, for that matter, $\mathbb{Q}[x]/(x^{3} - 2)$?
I'm just being introduced to field theory, and I'm not comfortable enough with some of these elementary concepts.
There are in general many different bases for $K$ as a vector space over $F$, and "the" basis you give above is in general not unique. The condition $\theta\equiv x\pmod{p(x)}$ is equivalent to $x-\theta$ dividing $p(x)$, i.e. to $\theta$ being a root of $p(x)$. Choosing different roots in general yields different bases for $K$ over $F$.
We cannot deduce this because $i\in\Bbb{C}$ is not an element of $\Bbb{R}[x]/(x^2+1)$. The two fields are isomorpic, but there is no canonical isomorphism between them. In fact there are precisely two isomorphisms (of fields) given by mapping $x$ to $i$ or mapping $x$ to $-i$, corresponding to different choices of roots of $x^2+1$ in $\Bbb{C}$. Alterrnatively, there are preciely two field automorphisms of $\Bbb{C}$ that are the identity on $\Bbb{R}$; these are the identity and complex conjugation.
This field can be embedded in $\Bbb{C}$, and even in $\Bbb{R}$. For the latter we must map the class of $x$ in $\Bbb{Q}[x]/(x^3-2)$ to $\sqrt[3]{2}\in\Bbb{R}$ so the embedding is unique and we may identify $\Bbb{Q}[x]/(x^3-2)$ with $\Bbb{Q}(\sqrt[3]{2})\subset\Bbb{R}$. Indeed $x^3-2$ has a unique root in $\Bbb{R}$. However, there are three distinct embeddings into $\Bbb{C}$ corresponding to three distinct roots of $x^3-2$ in $\Bbb{C}$, so again we cannot identify the class of $x$ in $\Bbb{Q}[x]/(x^3-2)$ with an element of $\Bbb{C}$ canonically.