I want to provide an example of a nonzero bounded linear functional on $L^\infty[0,1]$ that vanishes on $C[0,1]$. I know that the existence of such a functional is guaranteed by the Hahn-Banach Theorem. My issue is with actually constructing one. For example, I know $C[0,1]$ is a subspace of $L^\infty[0,1]$, so I tried defining a functional $f$ on $C[0,1]$ as $f(u)=\lim_{x\to\frac{1}{2}^+}u(x)-\lim_{x\to\frac{1}{2}^-}u(x)$. This vanishes on $C[0,1]$ but the one-sided limits are not necessarily well-defined on $L^\infty[0,1]$. I also thought of considering $L:=$ the span of $C[0,1]$ and some element in $L^\infty[0,1]\backslash C[0,1]$ like $\chi_{[0,\frac{1}{2}]}$. Then for $y=u+\lambda\chi_{[0,\frac{1}{2}]}\in L$, I can define $f(y)=\lambda$.
$f$ vanishes on $C[0,1]$ and $||f||\neq0$ and I know I can extend $f$ to $\phi$ on $L^\infty[0,1]$ but I want to be able to know what $\phi$ looks like explicitly. Maybe that is not possible for this $\phi$, but is there an example of some other $\phi$ that is explicitly defined for every element in $L^\infty[0,1]$?
The bounded linear functionals on $L^\infty[0,1]$ are precisely those given by integration against finitely additive complex measures that are absolutely continuous with respect to Lebesgue measure. So what you are looking for is an example of an additive but $\sigma$-additive measure. And the examples are not terribly explicit: here is the kind of thing to expect.