The beginning of the power series of the tangent function is given by $$\tan(x) = x+\frac{x^3}{3}+\frac{2\,x^5}{15}+\frac{17\,x^7}{315}+ \frac{62\,x^9}{2835}+\frac{1382\,x^{11}}{155925}+\frac{21844\, x^{13}}{6081075}+\frac{929569\,x^{15}}{638512875}+\frac{6404582 \,x^{17}}{10854718875}+\frac{443861162\,x^{19}}{1856156927625} +\cdots $$
Do the odd coefficients of the series form a decreasing sequence?
It seems so. The (2n-1)th coefficient of the series is given by $$ a_n = 4^n(4^n-1)|B_{2n}|/(2n)! $$ where $B_n$ is the Bernoulli numbers. I don't know how to evaluate the quotients of the successive even Bernoulli numbers though.
The asymptotics of Bernoulli numbers of even index is $$B_{2 n} \sim(-1)^{n+1} \,4 \sqrt{\pi n}\, \left(\frac{n}{\pi e}\right)^{2 n}$$ (have a look here).
This is a very good a)pproximation : relative error smaller than $1.0$% for $n=5$, smaller than $0.1$% for $n=42$.
So, if
$$a_n=4^n(4^n-1)\frac{|B_{2n}|} {(2n)!}\quad \implies \quad a_n \sim \frac{4^{n-3} \left(1152 n^2-48 n+1\right) }{9 n^2 \, \pi ^{2 n}}$$ $$\frac{a_{n+1}}{a_n}=\frac{4 n^2 \left(1152 n^2+2256 n+1105\right)}{\pi ^2 (n+1)^2 \left(1152 n^2-48 n+1\right)}$$
Expanding as a Taylor series $$\frac{a_{n+1}}{a_n}=\frac 4{\pi^2} \left(1+\frac{1}{24 n^2}-\frac{1}{24n^3}+O\left(\frac{1}{n^4}\right)\right)$$
Using your last coefficients $$\frac {a_{19}}{a_{17}}=\frac{221930581}{547591761}=0.405285$$ wile the truncated series gives $$\frac {a_{19}}{a_{17}}\sim \frac{58964}{14739 \pi ^2}=0.405340$$
Edit
Interesting is the approximation
$$|B_{2 n}| \sim 4\,\sqrt{\pi n}\, \left(\frac n{\pi e}\, \frac{480 n^2+9}{480 n^2-1}\right)^{2n}$$ which is much more accurate and gives
$$\frac{a_{n+1}}{a_n}=\frac 4{\pi^2} \left(1+\frac{2369}{23224320n^6}+O\left(\frac{1}{n^7}\right)\right)$$ which gives
$$\frac {a_{19}}{a_{17}}\sim \frac{560578626480449}{140144656619520 \pi ^2}$$ which differs from the exact value by $9.32\times 10^{-10}$.
Update
If we consider instead $${a_{n+1} \over a_n} = \Bigl(4+{3 \over 4^{n}-1}\Bigr) {1 \over \pi^2} {\zeta(2n+2) \over \zeta(2n)} $$
$$ {\zeta(2n+2) \over \zeta(2n)}~>~ 4 \,\frac{2^{2 n-1}-1}{2^{2 n+1}-1}$$ would be very useful