Let $X_n\sim \text{Poi}(\lambda_n)$, with $X_i$'s independent and $\sum\limits_{n=1}^\infty\lambda_n=\infty.$ Define $S_n=\sum\limits_{i=1}^nX_i$ . Is it true that $${S_n\over \Bbb E (S_n)}$$ converges in probability?
I don't know what it converges to, but I guess it should be $1$.
Yes, your guess is correct. Since the sum of independent Poisson r.v.'s is again Poisson with parameter the sum of the parameters, you know that $$σ^2_n=\text{Var}(S_n)=\mathbb E[S_n]=\sum_{k=1}^nλ_n$$ and hence by Chebyshev's inequality \begin{align}P\left(\left|\frac{S_n}{\mathbb E[S_n]}-1\right|\ge\epsilon\right)&=P\left(\left|S_n-\mathbb E[S_n]\right|\ge σ_n^2\epsilon\right)\\[0.3cm]&=P\left(\left|S_n-\mathbb E[S_n]\right|\ge σ_n\cdot(σ_n\epsilon)\right)\le^{\text{Chebyshev's inequality}}\\[0.3cm]&\le\frac{1}{(σ_n\epsilon)^2}=\frac{1}{\epsilon^2\sum_{k=1}^nλ_k}\longrightarrow 0\end{align} as $n\to\infty$ for any $\epsilon >0$.