Let $ \Psi$ be a set of functions $\chi :\mathbb{R}^+\rightarrow [0,1)$ satisfying $$\chi(t_n)\rightarrow 1\Rightarrow t_n\rightarrow 0$$
I want to find some functions that belongs to $ \Psi$, other than
$\chi_1 (t)=\left\{\begin{matrix} e^{-2t} & \text{if } t>0\\ 1 & \text{if } t=0 \end{matrix}\right.$
$\chi_2 (t)=\left\{\begin{matrix} \frac{1}{1+t} & \text{if } t>0\\ 1 & \text{if } t=0 \end{matrix}\right.$
I'm working on this kind of functions, and i want to know more about it.
Edit: I've updated this post to match the corrected condition. As I had predicted, the updated version is very similiar to the original.
The condition $\chi(t_n) \to 1 \implies t_n \to 0$ is equivalent to (for functions $[0,\infty) \to [0,1)$):
I.e., the function is bounded away from $1$ everywhere except possibly at $t = 0$.
Your condition does not require any behavior for $\chi$ near $0$. It could be that $\lim_{t\to 0} \chi(t) = 1$, but it could also be true that $\chi$ is bounded away from $1$ everywhere. In that case, there are no sequences $\{t_n\}$ such that $\chi(t_n) \to 1$, so your condition is vacuously true.
Any function bounded away from $1$ is an example:
Functions that satisfy the condition, but are not bounded away from $1$ near $0$ include the two you've already given, and
The boundedness condition is clearly sufficient to imply yours. To show that it is also necessary, first note that if $\chi$ is not bounded away from $1$ at some $p > 0$, then one can always find a $t_n \in (p - 1/n, p + 1/n)$ with $\chi(t_n) > 1 - 1/n$, and therefore $\chi(t_n) \to 1$ while $t_n \to p$. A similar argument holds for $p = \infty$. Thus every point in $[\epsilon, \infty]$ has a neighborhood bounded away from $1$. By compactness, a finite number of those neighborhoods covers it. The highest bound among the neighborhoods in the finite cover serves as $1-m_\epsilon$.