Once you see the notion of vector bundle, next thing you want to see are examples of non trivial vector bundles.
Here, I want to collect such examples with justification of one or two lines saying why this vector bundle is non trivial.
Please add one per answer.
The usual example is the Möbius bundle. Let $X = [0,1]\times\mathbb{R}$, and define an equivalence relation $\sim$ where $(0,y)\sim(1,-y)$. Let $E = X/\sim$ be our total space and let $M = [0,1]$. Then a vector bundle $\pi:E \rightarrow M$ is given by $[(x,y)] \mapsto x$.
Edit to give a justification: if $E$ were trivial, then it would admit a smooth global frame, or a non-vanishing, smooth, global section. This would amount to a nonvanishing function $f : [0,1] \mapsto \mathbb{R}$ with $f(0) = -f(1)$, which can't exist according to the intermediate value theorem.