Consider, for $\zeta_5$ the fifth root of unity, $\alpha := \zeta_5^2 + \zeta_5^3 ∈ ℂ$.
To demonstrate: $[ℚ(α): ℚ] = 2$.
We know that $\zeta_5$ is a root of the cyclotomic polynomial $f := \frac{X^5-1}{X-1} = X^4 + X^3 + X^2 + X +1 ∈ ℤ[X]$. As it is monic and irreducible, we must in fact have that $f = f^{ζ_5}_ℚ$ (the minimum polynomial of $ζ_5$ over ℚ) and hence $[ℚ(ζ_5): ℚ] = \deg f = 4$.
How then can $[ℚ(α): ℚ]$ be 2? Or have I already concluded something wrongly?
Edit
Without resorting to trigonometric identities (because the end game here is to derive them), does this allow one to prove that $ℚ(\alpha) = ℚ(√{5})$?
As you note $[\Bbb{Q}(\zeta_5):\Bbb{Q}]=4$ and clearly $\alpha\in\Bbb{Q}(\zeta_5)$, so you have a tower of fields $$\Bbb{Q}\subset\Bbb{Q}(\alpha)\subset\Bbb{Q}(\zeta_5).$$ The degree is multiplicative over towers of fields so $[\Bbb{Q}(\alpha):\Bbb{Q}]$ must divide $[\Bbb{Q}(\zeta_5):\Bbb{Q}]=4$.
As you know, the first four powers of $\zeta_5$ form a basis for $\Bbb{Q}(\zeta_5)$ as a vector space over $\Bbb{Q}$. From this it is immediate that $\alpha\notin\Bbb{Q}$, which shows that $[\Bbb{Q}(\alpha):\Bbb{Q}]\neq1$. To determine whether the degree equals $2$ or $4$ you can compute a few powers of of $\alpha$: If the degree is $2$ then $\alpha^0,\alpha^1,\alpha^2\in\Bbb{Q}(\alpha)$ must be linearly dependent over $\Bbb{Q}$. A few simple computations show that \begin{eqnarray*} \alpha^0&=&1=\zeta_5^0,\\ \alpha^1&=&\zeta_5^2+\zeta_5^3,\\ \alpha^2&=&(\zeta_5^2+\zeta_5^3)^2=\zeta_5^4+2\zeta_5^5+\zeta_5^6=2+\zeta_5+\zeta_5^4, \end{eqnarray*} where we used the fact that $\zeta_5^5=1$. Now keep in mind that $1+\zeta_5+\zeta_5^2+\zeta_5^3+\zeta_5^4=0$, so $$\alpha^2+\alpha-1=0.$$ This shows that $\Bbb{Q}(\alpha)$ is a quadratic extension of $\Bbb{Q}$.