A relation is defined by: $x\leq y$ if and only if there exists $\in \mathbb{N}$ such that $y= x+5k$. Prove that $\leq$ is a partial order.
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A relation "$\leq$" is a partial order if it is
This is clear since $x=x+5\cdot 0$, assuming your set of natural numbers includes $0$.
If $x\leq y$ and $y\leq x$ then by definition there exist $k_1,k_2\in \mathbb{N}$ such that $x=y+5k_1$ and $y=x+5k_2.$ Solving these two equations you find that $k_1=-k_2.$ and thus $k_1=k_2=0$ since $k_1,k_2\in \mathbb{N}$. Hence $x=y$.
Since $x\leq y$ and $y\leq z$, there exist $m_1,m_2\in \mathbb{N}$ such that $x=y+5m_1$ and $y=z+5m_2.$ From these two equations you have $x=z+5(m_1+m_2)$ and since $m_1+m_2\in \mathbb{N}$, $x\leq z$.