You select 10 numbers from the set $\{2,3,\dots,12\}$. You then continually roll 2 fair dice and sum them up, until your selection of 10 numbers come up.
For example if your selection was 7,7,7,7,8,8,8,6,6,6 (4 7's, 3 8's and 3 6's), and you roll the dice repeatedly and get 7,7,6,5,8,7,7,9,8,3,5,10,12,6,6,3,2,5,7,9,8, you may stop now because 4 7's have come up, 3 8's and 3 6's.
What is the best choice of 10 numbers so as to minimise the number of rolls ?
(too long for a comment, but not a full answer). I'll work it out for $n=2$, $n$ being the number of values you select.
Let $E[a,b]$ be the expected number of throws it take assuming you chose $a,b$. Similarly, let $E[a]$ be the expected number of throws it takes just to see $a$. Of course $E[a]=\frac 1{P(a)}$.
For $a=b$ clearly choosing $7$ is best. In that case one sees at once that $$\boxed{E[7,7]=\frac 2{P(7)}=12}$$
Now assume that $a\neq b$.
Considering the possible outcomes of the first toss (i.e. "$a$", "$b$", or neither) it is easy to see that $$E[a,b]=P(a)\times \left(E[b]+1\right)+P(b)\times \left(E[a]+1\right)+(1-P(a)-P(b))\times \left(E[a,b]+1\right)$$
This implies that $$\boxed {E[a,b]=\frac {P(a)P(b)+P(a)+P(b)}{P(a)P(b)(P(a)+P(b))}}$$
It is easy to compute that $$E[7,8]=E[7,6]=9.92727\cdots<12$$ and that $$E[6,8]=10.8$$ so as the OP expected, choosing $\{7,6\}$ or $\{7,8\}$ is optimal. (remark: it is not difficult to rule out the other possibilities, by direct computation if nothing else.)
Note I: this method generalizes to more choices but the cases start to multiply badly. My guess for $n=3$ would be $\{6,7,8\}$ but I have not verified this and it could easily be incorrect.
Note II: this method certainly lends itself to automation. If you have computed all the expectations for $n$ choices then you can get them for $n+1$ by a recursion as was done above. This is hardly a pencil and paper method, however. there are $\binom {19}9=92378$ possible selections when $n=9$ and $\binom {20}{10}=184756$ when $n=10$.