Let $\alpha\in \overline {\mathbb F_2}$ (the algebraic closure of $\mathbb F_2$ ) be such that $\mathbb F_2[\alpha]$ is a field of order $2^n$ (where $n>1$).
Then is it true that $\alpha \in \mathbb F_2[\alpha]^{\times}$ generates the multiplicative group $\mathbb F_2[\alpha]^{\times}$ i.e. is $2^n-1$ the multiplicative order of $\alpha$ ?
Not necessarily. For instance $f(x)=x^4+x^3+x^2+x+1$ is irreducible over $\Bbb F_2$, so a solution $\alpha$ of $f(x)=0$ generates $\Bbb F_{16}$. But $\alpha$ has multiplicative order $5$ and does not generate $\Bbb F_{16}^\times$.