I'm trying to prove that when $\mathbb{R}$ has the countable complement topology, it is not path connected.
I used the following definition of continuous: $f(\overline{A})\subset\overline{f(A)}$.
We want to show that some path $f: [0,1] \rightarrow{} \mathbb{R}$ cannot be continuous. Taking $A=\mathbb{Q} \cap [0,1]$, we get that $f(\overline{A})=f([0,1])$, which is uncountable (by density of rationals within the reals). However, $f(A)$, which is countable, has no limit points in the countable complement topology (for each other point, one can construct a neighborhood that avoids exactly the countably many points in $f(A)$). This means that $\overline{f(A)}=f(A)$ is also countable. However, an uncountable set cannot be a subset of a countable set.
Does this proof seem sufficient?
I'm not sure what you mean by "density of rationals within the reals" - the reals with this topology are not separable, and thus the rationals cannot be a dense subset. (In fact, the rationals are closed as they are countable.)
This is S17 of the pi-Base, and example #20 in Steen/Seebach's Counterexamples in Topology. The pi-Base deduces this space is not path connected based on the fact that all anticompact $T_1$ spaces are totally path disconnected.
To see this, let $f:[0,1]\to\mathbb R$ be a path. Then $f([0,1])$ must be compact and connected as the continuous image of a compact and connected space. Since $\mathbb R$ only has finite sets as compact sets, and the only finite connected $T_1$ space is the singleton, every path is a single point.
To see that your space is $T_1$, note $\mathbb R\setminus\{x\}$ is open and thus singletons are closed. To see that your space is anticompact, let $Y\subseteq\mathbb R$ be infinite, and let $\{y_n:n<\omega\}\subseteq Y$ be distinct. Then $\{\mathbb R\setminus\{y_n:N\leq n<\omega\}:N<\omega\}$ is an open cover of $Y$ with no finite subcover, showing it is not compact.