I was proving implications of Dominated Convergence Theorem, $\sup_n \mathbf{E}|X_n| < \infty$ if $X_n$ is uniformly integrable, and had this confusion:
If there's a finite collection of uniformly integrable rvs $\{X_n\}$, is $\sup_n\mathbf{E}X_n = \mathbf{E}\sup_nX_n$? I think it is.
I define $X^{\ast}=\sup_n X_n$; the collection of rvs can be ordered, i.e. $\{X_{a_1} \leq X_{a_2} \leq \ldots X^{\ast}\}$ for some sequence if indices $a_j$ and all $\omega \in \Omega$. Since $\mathbf{E}$ is order-preserving, this ordering applies to expectations $\{\mathbf{E}X_{a_1} \leq \mathbf{E}X_{a_2} \leq \ldots \mathbf{E}X^{\ast}\}$. By definition, $\mathbf{E}X^{\ast} = \mathbf{E}\sup_n X_n$. From the second ordering, $\mathbf{E}X^{\ast} = \sup_{a_j} \mathbf{E}X_{a_j} = \sup_n \mathbf{E}X_n$, proving the statement.
If this is correct, I can prove, using uniform integrability, for any number $\alpha \to \infty$ \begin{align} \mathbf{E}X^{\ast} &\leq \mathbf{E}|\sup_n X_n|\leq \color{red}{\mathbf{E}\sup_n|X_n| = \sup_n \mathbf{E} |X_n|} \\ &= \sup_n \mathbf{E}\big(|X_n|I_{|X_n|> \alpha} + |X_{n}|I_{|X_{n}| \leq \alpha} \big) \to_{\alpha} \sup_n \big( 0 + \mathbf{E}|X_{n}| \big)\\ &< \sup_n c = c <\infty \end{align} as required. The last inequality is by definition of integrability, $\int_{\mathbb{R}}|X|< c< \infty$. The step I proved is in red. Note I don't use convergence anywhere except the upper bound on the Lebesgue integral.
The best you can say is: $E\sup |X_n| \ge \sup E(|X_n|)$, even if you have a finite number of $X$'s. So unfortunately this inequality goes the wrong way for you.
Example: On the unit interval equipped with Lebesgue measure, take $n=2$, with $X_1:=I_{[0,\frac12]}$ and $X_2:=I_{[\frac12,1]}$. Compute $E(|X_n|)=\frac12$ for $n=1,2$, while $\sup |X_n|$ is identically 1.