If we assume $X$ to be a normal distributed random variable, then we can prove than $\Bbb P(X<mean) = \Phi(0) = 0.5$. This is true for any symmetric distribution.
I'm not sure how to prove/disprove it for an asymmetric (around mean) PDF. We're basically trying to see if mean is always the $50\%$ percentile.
Let $X \sim \operatorname{Exp}(1)$. The mean is $$E[X]=1 ,$$ while the median is $\log(2)$.