How can I show $\mathbb{Q}(\alpha)\cap\mathbb{R}=\mathbb{Q}$ where $\alpha=\sqrt{\frac{3+\sqrt{7}i}{2}}$?
$\alpha$ is a root of a degree 4 irreducible polynomial over $\mathbb{Q}$, so $\mathbb{Q}(\alpha):\mathbb{Q}$ is a degree 4 extension and has as basis $1,\alpha,\alpha^2,\alpha^3$. We can write an arbitrary non-rational element of $\mathbb{Q}(\alpha)$ as a $\mathbb{Q}$-linear combination of these basis elements, but after that I'm not sure how to proceed.
If you are really interested in determining the Galois group, observe that the Galois closure is $L=K(\alpha,\beta)$, where $K=\Bbb Q(i\sqrt7)$ and $\alpha^2=\frac12(3+i\sqrt7)$ and $\beta^2=\frac12(3-i\sqrt7)$. Thus $L/K$ is a Kummer extension, and its degree is the order of the subgroup of $K^\times/(K^\times)^2$ generated by the $\frac12(3\pm i\sqrt7)$.
The norm of $\frac12(3+i\sqrt7)$ is $4$ which suggests it may be a square of a norm $2$ algebraic integer. But $\left[\frac12(1-i\sqrt7)\right]^2= \frac12(-3-i\sqrt7)$. Thus $\alpha=\pm i\frac12(1-i\sqrt7)$. Likewise $\beta=\pm i\frac12(1+i\sqrt7)$.
Then $L=\Bbb Q(\alpha)=\Bbb Q(i,\sqrt7)$. This has Galois group $(C_2)^2$. Also $\Bbb Q(\alpha)\cap\Bbb R=\Bbb Q(\sqrt7)$.