So I have this problem here.
The probability that Tom is late for work on a rainy day is 0.4 and the probability that he is late for work on a non-rainy day is 0.1.
Can I state that P(Tom being late for work)=P(Late|Rain)+P(Late|No rain)=0.4+0.1=0.5 ?
Assuming that "the probability that tom is late for work on a rainy day" is in reference to $Pr(\text{Late}\mid \text{Rain})$ then no. You need to know the probability of it being a rainy day. The correct statement would be:
$Pr(\text{Late}) = Pr(\text{Rain})Pr(\text{Late}|\text{Rain}) + Pr(\text{No rain})Pr(\text{Late}|\text{No rain})$
This is the law of total probability.