There is a natural homomorphism
$$\phi:F[x]\to F(\alpha)$$
$$\phi(p(x))=p(\alpha)$$
obtained by a mapping which leaves coefficient of polynomial unchanged and sends $x$ to $\alpha$.
Clearly $m_\alpha(x)\in \operatorname{ker}\phi$. Where $\operatorname{ker}\phi=\{p(x)\in F[x]:p(\alpha)=0\}$. So we obtain an induced homomorphism:
$$\phi:F[x]/(m_\alpha(x))\to F(\alpha).$$
$F[x]$ is P.I.D. which is generated by unique monic polynomial $m_\alpha(x)$. which is irreducible since the homomorphism $\phi$ is a surjection onto the field $F(\alpha)$.
Therefore $F[x]/(m_\alpha(x))$ is a field. the map $\phi$ is not the zero map . Therefore , $\phi$ is injective ring homomorphism. By the definition of $F(\alpha)$ the map $\phi$ must be surjective.
It follows that $\phi$ is isomorphism. Hence $F[x]/(m_\alpha(x))\cong F(\alpha)$.
Is the proof correct?
First of all we prove a lemma then we prove the main theorem
Lemma: Let $L/K$ is a field extension. Let $\alpha\in L$ is algebraic over $K$. Then the minimal polynomial in $\alpha$ over $K$ is unique and irreducible.
Proof: let $m_\alpha(x)$ be a minimal polynomial with degree $n$. By the uniqueness of minimal polynomial we have that $m_\alpha(x)$ is unique minimal polynomial. Let us assume that leading coefficient of $m_\alpha(x)$ is $1$ (because $K$ is a field). Assuming the contrary. Suppose $m_\alpha(x)$ is reducible. Then there exist non-constant polynomial $g(x),h(x)\in K[x]$ such that: $m_\alpha(x)=g(x)h(x).$ $\Rightarrow$ $g(\alpha)h(\alpha)=0$. Then either $h(\alpha)=0$ or $g(\alpha)=0$(Since $L$ is an integral domain). contradict the minimality of $m_\alpha(x)$.
Proof of the main theorem
Proof: There is a natural homomorphism
$$\phi:F[x]\to F(\alpha)$$
$$\phi(p(x))=p(\alpha)$$
obtained by a mapping which leaves coefficient of polynomial unchanged and sends $x$ to $\alpha$.
Clearly $m_\alpha(x)\in \operatorname{ker}\phi$. Where $\operatorname{ker}\phi=\{p(x)\in F[x]:p(\alpha)=0\}$. So we obtain an induced homomorphism:
$$\phi:F[x]/(m_\alpha(x))\to F(\alpha).$$ $\alpha\in F(\alpha)$ is algebraic over $F$. Then the minimal polynomial $m_\alpha(x)$ over $F$ is unique and irreducible polynomial(By above Lemma). Therefore $F[x]/(m_\alpha(x))$ is a field. the map $\phi$ is not the zero map . Therefore , $\phi$ is injective ring homomorphism. Since $\operatorname{Im}\phi$ is isomorphic to its image which is a subfield of $F(\alpha)$(By $1^{st}$ isomorphosm theorem). By the definition of $F(\alpha)$ the map $\phi$ must be surjective. It follows that $\phi$ is isomorphism. Hence $F[x]/(m_\alpha(x))\cong F(\alpha)$