Is it possible to simplify the ratio $$\mathcal{E}=\frac{_3F_2\left(\frac{1}{2},\frac{3}{4},\frac{5}{4};\ 1,\frac{3}{2};\ \frac{3}{4}\right)}{\Pi\left(\frac{1}{4}\Big|\frac{1}{\sqrt{3}}\right)},$$ where $\Pi(n|k)$ is the complete elliptic integral of the third kind?
Its numeric value is approximately $\mathcal{E}\approx0.73510519389572273268...$, that looks like $\frac{4}{\pi\sqrt{3}}$.