After having seen a lengthy and painful calculation showing $\operatorname{Gal}(\mathbb Q[e^\frac{2\pi i}3, \sqrt[\leftroot{-2}\uproot{2}3]{2}]/\mathbb Q)\cong S_3$, I'm wondering whether there's a slick proof $\operatorname{Gal}(\mathbb Q[e^\frac{2\pi i}p, \sqrt[\leftroot{-2}\uproot{2}p]{2}]/\mathbb Q)\cong S_p$ for odd prime $p$, because these calculations are getting intractable fast.
What are some slick proofs of this fact (assuming it is indeed correct).
Correction: What IS $\operatorname{Gal}(\mathbb Q[e^\frac{2\pi i}p, \sqrt[\leftroot{-2}\uproot{2}p]{2}]/\mathbb Q)$ for prime $p$?
Your statement does not hold. Let $\zeta$ be some $p$-th root of unity. Remember that the order of the galois group $\text{Gal} \mathbb{Q}(\zeta, \sqrt[p]{2})$ is the degree of the extension $\mathbb{Q}(\zeta, \sqrt[p]{2})/ \mathbb{Q}$. Now $[\mathbb{Q}(\zeta) : \mathbb{Q}]=p-1$ and $[\mathbb{Q}(\sqrt[p]{2}) : \mathbb{Q}]=p$ because $X^p-2$ is irreducible by eisenstein. We have $[\mathbb{Q}( \zeta, \sqrt[p]{2}) : \mathbb{Q}( \sqrt{2} ) ] \leq p$ but $p \mid [ \mathbb{Q}(\zeta, \sqrt[p]{2}) : \mathbb{Q}]=[\mathbb{Q}(\zeta, \sqrt[p]{2}) : \mathbb{Q}(\zeta)][\mathbb{Q}(\zeta): \mathbb{Q}]= [\mathbb{Q}(\zeta, \sqrt[p]{2}) : \mathbb{Q}(\zeta)](p-1)$, by euclid's lemma we have $p \mid [\mathbb{Q}(\zeta, \sqrt[p]{2}) : \mathbb{Q}(\zeta)]$ because $ \gcd(p, p-1) =1 $. So $p=[\mathbb{Q}(\zeta, \sqrt[p]{2}) : \mathbb{Q}(\zeta)]$.
Conclusion: $[\mathbb{Q}(\zeta, \sqrt[p]{2}) : \mathbb{Q}]=p(p-1)$. Now if your statement would hold, then $p(p-1)=|S_p|=p!$. This is true for odd $p$ exactly when $p=3$. So for any other odd $p$ this is not true.