When I look at the rules of inference, $$ \begin{align} \land \ \mathrm{I}& \ \frac{p \ \ \ \ \ q}{p \land q} \ \ \ \ \ \ \ \ &\frac{p \land q}{p \ \ \ \ \ q} \land \mathrm{E} \\ \\ \not\rightarrow \mathrm{I}& \ \frac{p \ \ \ \ \lnot q}{p \not\rightarrow q} \ \ \ \ \ \ \ \ &\frac{p \not\rightarrow q}{p \ \ \ \ \lnot q}\not\rightarrow \mathrm{E} \\ \\ \not\leftarrow \mathrm{I} & \ \frac{\lnot p \ \ \ \ \ \ q}{p \not\leftarrow q} \ \ \ \ \ \ \ &\frac{p \not\leftarrow q}{\lnot p \ \ \ \ \ q }\not\leftarrow \mathrm{E} \\ \\ \downarrow \mathrm{I}& \ \frac{\lnot p \ \ \ \lnot q}{p \downarrow q} \ \ \ \ \ \ \ \ &\frac{p \downarrow q}{\lnot p \ \ \ \ \lnot q} \downarrow \mathrm{E} \end{align} $$ and the truth table, $$\begin{array}{c|c} p & q & \lnot p & \lnot q & p \land q & p \not\rightarrow q & p \not\leftarrow q & p \downarrow q \\ \hline 1 & 1 & 0 & 0 & 1 & 0 & 0 & 0 \\ 1 & 0 & 0 & 1 & 0 & 1 & 0 & 0 \\ 0 & 1 & 1 & 0 & 0 & 0 & 1 & 0\\ 0 & 0 & 1 & 1 & 0 & 0 & 0 & 1 \\ \end{array}$$ for connectives that have only one occurrence of $1$ in their column in a truth table (i.e, $\land, \not\rightarrow, \not\leftarrow, \downarrow $) I'm able to see the connection between the truth table and the rules of inference; the thing(s) on the top part of the rule evaluate(s) to $1$ on the truth table if and only if the thing(s) on the bottom part of the rule evaluate(s) to $1$ on the truth table.
Clearly this observation doesn't extend to any of the other connectives. Most curious to me, the rules for the connectives that have only one occurrence of $0$ in their column in a truth table (i.e., $\lor, \rightarrow, \leftarrow, \uparrow$) are kind of 'ugly', and some seem to have no obvious connection to truth tables at all. $$ \lor \ \mathrm{I} \ \frac{p}{p \lor q} \ \ \ \ \ \ \ \lor \mathrm{I} \ \frac{q}{p \lor q} \ \ \ \ \ \ \ \ \frac{p \rightarrow r \ \ \ q \rightarrow r \ \ \ p \lor q}{r} \lor \mathrm{E} $$ $$ \rightarrow \mathrm{I} \ \frac{p ⟹ q}{p \rightarrow q} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \frac{p \ \ \ \ p \rightarrow q}{q}\rightarrow \mathrm{E} $$ $$ \leftarrow \mathrm{I} \ \frac{p ⟸ q}{p \leftarrow q} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \frac{p \leftarrow q \ \ \ \ q}{p}\leftarrow \mathrm{E} $$ $$ \uparrow \mathrm{I} \ \frac{p ⟹ r}{p \uparrow (q \uparrow r)} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \frac{p \ \ \ \ p \uparrow (q \uparrow r)}{r} \uparrow \mathrm{E} $$ If we had two 'provability' relations where the standard one is modelled off of $\rightarrow$ ($⟹$) and nonstandard one is modelled off of $\not\rightarrow$, would the rules for all or any of the ($\lor, \rightarrow, \leftarrow, \uparrow$)-connectives under the nonstandard relation look like the rules for the ($\land, \not\rightarrow, \not\leftarrow, \downarrow $)-connectives under the standard ($⟹$) relation?
UPDATE:
In the original post I made a comment about how the space between premises in a rule is treated like 'and', which lemontree addressed in their answer. Instead of having the space be treated as an 'and' (or 'or'), I am going to explicitly write '$\color{red}{ and }$' (or '$\color{blue}{ or }$') in when that is what is meant.
$ \color{red}{ ⟹ } , \color{red}{⟸}$, and $\color{red}{⟺}$ should be seen the same as the standard reading of $⊢, ⊣$, and $⊣⊢$. For example, $p \color{red}{ \ and \ } q \color{red}{ ⟹ } p \land q$ should be thought of as $p, q ⊢ p \land q$. I mentioned in the original post that that the syntactic relation $⊢$ ($\color{red}{ ⟹ }$) is "modelled off of" the logical connective $\rightarrow$, which Bram28 addressed in their answer. In the same way that $\color{red}{⟺}$ is connected with $\leftrightarrow$, I want to introduce another type of syntactic relation, $\color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}}$, which is meant to have an analogous connection with $\nleftrightarrow$. I hope what I have in mind becomes clear with the (currently incomplete) list below: $$ \begin{align} p \color{red}{ \ and \ } q \color{red}{ ⟺ } p &\land q \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{blue}{ \ or \ } \lnot q \\ p \color{red}{ \ and \ } \lnot q \color{red}{ ⟺ } p &\not\rightarrow q \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{blue}{ \ or \ } q \\ \lnot p \color{red}{ \ and \ } q \color{red}{ ⟺ } p &\not\leftarrow q \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} p \color{blue}{ \ or \ } \lnot q \\ \lnot p \color{red}{ \ and \ } \lnot q \color{red}{ ⟺ } p &\downarrow q \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} p \color{blue}{ \ or \ } q \\ p \color{blue}{ \ or \ } q \color{red}{ ⟺ } p &\lor q \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{red}{ \ and \ } \lnot q \\ p \color{blue}{ \ or \ } \lnot q \color{red}{ ⟺ } p &\leftarrow q \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{red}{ \ and \ } q \\ \lnot p \color{blue}{ \ or \ } q \color{red}{ ⟺ } p &\rightarrow q \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} p \color{red}{ \ and \ } \lnot q \\ \lnot p \color{blue}{ \ or \ } \lnot q \color{red}{ ⟺ } p &\uparrow q \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} p \color{red}{ \ and \ } q \\ ? \color{red}{ ⟺ } p &\leftrightarrow q \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} ? \\ ? \color{red}{ ⟺ } p &\not\leftrightarrow q \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} ? \\ \lnot p \color{red}{\ and \ } \lnot p? \color{red}{ ⟺ } \ \ & \lnot p \ \ \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} p \color{blue}{\ or \ } p? \\ \lnot q \color{red}{\ and \ } \lnot q? \color{red}{ ⟺ } \ \ & \lnot q \ \ \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} q \color{blue}{\ or \ } q? \\ p \color{red}{\ and \ } p? \color{red}{ ⟺ } \ \ & \ \ p \ \ \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{blue}{\ or \ } \lnot p? \\ q \color{red}{\ and \ } q? \color{red}{ ⟺ } \ \ & \ \ q \ \ \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot q \color{blue}{\ or \ } \lnot q ? \\ p \color{blue}{\ or \ } \lnot p? \color{red}{ ⟺ } \ \ &\ \ 1 \ \ \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{red}{\ and \ } p ? \\ p \color{red}{\ and \ } \lnot p? \color{red}{ ⟺ } \ \ &\ \ 0 \ \ \ \color{blue}{ \require{enclose} \enclose{verticalstrike}{⟺}} \lnot p \color{blue}{\ or \ } p? \\ \end{align} $$
In this list the connectives that I thought had unintuitive rules under the standard syntactic relation (i.e., $\lor, \leftarrow, \rightarrow, \uparrow$) would have simple rules if the space was either interpreted as 'or' (instead of 'and') or if the rule was a rule for the second type of syntactic relation (the blue one). For example, $$ \land \ \mathrm{I} \ \color{red}{ \frac{\color{black}{p} \color{red}{ \ and \ } \color{black}{q}}{\color{black}{p \land q}}} \ \ \ \ \ \ \ \ \ \color{red}{ \frac{\color{black}{p \land q}}{\color{black}{p} \color{red}{ \ and \ } \color{black}{q}}} \land \mathrm{E} \\ \ \\ \uparrow \ \mathrm{I} \ \color{blue}{ \frac{\color{black}{p} \color{red}{ \ and \ } \color{black}{q}}{\color{black}{p \uparrow q}}} \ \ \ \ \ \ \ \ \ \color{blue}{ \frac{\color{black}{p \uparrow q}}{\color{black}{p} \color{red}{ \ and \ } \color{black}{q}}} \uparrow \mathrm{E} \\ \ \\ \lor \ \mathrm{I} \ \color{red}{ \frac{\color{black}{p} \color{blue}{ \ or \ } \color{black}{q}}{\color{black}{p \lor q}}} \ \ \ \ \ \ \ \ \ \color{red}{ \frac{\color{black}{p \lor q}}{\color{black}{p} \color{blue}{ \ or \ } \color{black}{q}}} \lor \mathrm{E} \\ \ \\ \downarrow \ \mathrm{I} \ \color{blue}{ \frac{\color{black}{p} \color{blue}{ \ or \ } \color{black}{q}}{\color{black}{p \downarrow q}}} \ \ \ \ \ \ \ \ \ \color{blue}{ \frac{\color{black}{p \downarrow q}}{\color{black}{p} \color{blue}{ \ or \ } \color{black}{q}}} \downarrow \mathrm{E} $$ I think this helps put into context why the rules for $\lor$ in the standard system looks strange (and in the standard system the rules for $\land$ look very simple) but in a nonstandard system the rules for $\lor$ are simple (and the nonstandard system the rules for $\land$ look strange).
At any rate, the entire bottom half of the list I made is just a best guess. The most confusing part is that I can't even guess what goes on the lines including $\leftrightarrow$ and $\not\leftrightarrow$ since it seems like I've already exhausted every possible combination of {$p,q,\lnot p, \lnot q$}{$\color{red}{and} , \color{blue}{or}$}{$p,q,\lnot p, \lnot q$} for each syntactic relation. What's going on here? I think this is at the heart of my question.
Please feel free to ask me for clarification about anything!
No.
By your I/E inference rules, $\not\to$ appears to be "not imply". $~~\lnot(p\to q)\iff p\land\neg q$
However, $\nvdash$ is "not provable", which by your truth-table semantics would mean "The consequent is valued $0$ in at least one row where all the antecedants are valued $1$".
That is: $p\nvdash q$ merely says, "If you assume $p$, then you may not infer $q$." ($q$ may or may not be true when $p$ is.)
(Not provable is not the same as disprovable.)