For simplicity's sake, let the Earth be a perfect sphere. Imagine you are drawing an equilateral triangle over its surface. How long should its sides be, for the sum of its angles to be 180.1 degrees?
What length would the sides of a triangle over Earth's surface be for the sum of its angles to be 180.1°
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Let $r$ be the radius of the Earth; the area of a triangle between the equator and two meridians $90^\circ$ apart is $\frac{r^2\pi}{2}$ and has a defect of $270^\circ-180^\circ=90^\circ$. Now we want a triangle with $900$ times smaller defect, which means it needs to have $900$ times smaller area: $\frac{r^2\pi}{1800}$.
Now I will not calculate the side for the spherical equilateral triangle (for the given area) but a planar one, expecting (without proof!) that this won't make a lot of difference. Thus, the side is approximately $\sqrt{\frac{4}{\sqrt 3}\frac{r^2\pi}{1800}}=r\sqrt{\frac{\pi}{450\sqrt 3}}\approx 404\text{ km}$.
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Consider an equilateral spherical triangle with side lengths $a$ and angles $A$, by the supplemental cosine rule https://en.wikipedia.org/wiki/Spherical_trigonometry#Identities
\begin{eqnarray*} \cos(A) =- \cos^2(A)+\sin^2(A) \cos(a) \\ \cos(a) =\frac{\cos(A)+\cos^2(A)}{\sin^2(A)} =\frac{\cos(A)}{1-\cos(A)} \end{eqnarray*} Now we have $A=60.0333\cdots$, which gives $a=3.6\cdots$.
To obtain the distance on a sphere of radius $r$ calculate $ra\pi/180$.

The area of a spherical triangle is exactly $ER^2$ where $E$ is the angular excess. In our case $E=\frac{\pi}{1800}$, so the given triangle covers $\frac{1}{7200}$ of Earth's surface. Assuming $R=1$, l'Huilier's formula (page 184 of my notes) relates the angular excess / the area to the semiperimeter / the side lengths through $$ \tan\frac{E}{4}=\sqrt{\tan\frac{s}{2}\tan\frac{s-a}{2}\tan\frac{s-b}{2}\tan\frac{s-c}{2}} $$ and in our case we have $a=b=c=\ell$ and $s=\frac{3}{2}\ell$, so
$$ E = \frac{\pi}{1800} = 4\arctan\sqrt{\tan\frac{3\ell}{4}\tan^3\frac{\ell}{4}} $$ and by solving $$ \tan\frac{3\ell}{4}\tan^3\frac{\ell}{4}=\tan^2\frac{\pi}{7200} $$ we get that $\ell$ is approximately $6.347\%$ of the radius $R$.
For Earth, $R =6\ 371$ km, and $\ell = 404.377$ km.