Since $\Bbb Q[\pi]$ consists of expressions of the form $$a_0 + a_1\pi + \ldots + a_n\pi^n \quad\quad a_i \in \Bbb Q$$ for $n\in \Bbb N$, the following isomorphism of sets is immediate: $$\Bbb Q[\pi] \cong \bigsqcup_{n\ge 1} \Bbb Q^n$$ It follows that $\Bbb Q[\pi]$ is countable, as it is a countable union of countable sets. Therefore, $\Bbb Q[\pi]$ is a proper subset of $\Bbb R$, an uncountable set. Certainly, all numbers in $\mathbb R \setminus \mathbb Q[\pi]$ are irrational, but I haven't been able to come up with a concrete example of an element in $\mathbb R \setminus \mathbb Q[\pi]$. Could someone throw some light on this problem? Thanks!
Note: This question arises purely from curiosity, so I am not sure how easy or difficult it is to answer in terms of the required mathematical machinery.
Let $\overline {\mathbb Q}$ denote the algebraic closure of $\mathbb Q$. Then $\overline{\mathbb Q} \cap \mathbb Q[\pi] = \mathbb Q$:
Suppose $p(\pi) \in \overline {\mathbb Q}$ for some polynomial with rational coefficients, then, as $\overline{\mathbb Q}$ is algebraically closed, either $\pi \in \overline{\mathbb Q}$ or $p(x)$ is a constant. We know that $\pi \notin \overline {\mathbb Q}$, hence $p(x) = q \in \mathbb Q$ is constant, which proves the statement above.
This shows that $(\overline {\mathbb Q}\cap \mathbb R) \setminus \mathbb Q \subseteq \mathbb R \setminus\mathbb Q[\pi]$, so we obtain many examples, including $\sqrt 2, \sqrt 3, \varphi$ etc. As the comments have already pointed out, it is very difficult to show that some non-algebraic numbers are not in $ {\mathbb Q}[\pi]$.