A brief answer: Let's consider the exponential function $e^x$. The definition of $e$ is that $\frac{d}{dx}e^x = e^x$. Now let's assume that $e^x$ can be written as an infinite sum of the form $\sum_{i=0}^{\infty}a_ix^i$. Using the sum rule for derivatives, we have $\sum_{i=0}^{\infty}a_ix^i = \sum_{i=0}^{\infty}\frac{d}{dx}a_ix^i = \sum_{i=1}^{\infty}ia_{i}x^{i-1}$. Therefore, $a_i = \frac{a_{i-1}}{i}$, so starting with the base case of $i=0$, $a_i = \frac{1}{i!}$.
(Warning: variables change from the previous section)
Another way to look at this is to consider the more standard definition of $e$, which is $\lim_{n\to\infty}(1 + \frac{1}{n})^n$. Therefore, $e^a$ can be written as $\lim_{n\to\infty}(1 + \frac{1}{n})^{an}$. Using the binomial theorem, the expression expands to $$\lim_{n\to\infty}(1 + \frac{an}{n} + \frac{an(an - 1)}{2n^2}+ \frac{an(an-1)(an-2)}{6n^3} + \ldots)$$ The lesser powers in the numerators drop out, so the expression becomes $$1 + a + \frac{a^2}{2} + \frac{a^3}{6} + \ldots$$which is $\sum_{i=0}^{\infty}\frac{a^i}{i!}$ in sum notation.
A brief answer: Let's consider the exponential function $e^x$. The definition of $e$ is that $\frac{d}{dx}e^x = e^x$. Now let's assume that $e^x$ can be written as an infinite sum of the form $\sum_{i=0}^{\infty}a_ix^i$. Using the sum rule for derivatives, we have $\sum_{i=0}^{\infty}a_ix^i = \sum_{i=0}^{\infty}\frac{d}{dx}a_ix^i = \sum_{i=1}^{\infty}ia_{i}x^{i-1}$. Therefore, $a_i = \frac{a_{i-1}}{i}$, so starting with the base case of $i=0$, $a_i = \frac{1}{i!}$.
(Warning: variables change from the previous section)
Another way to look at this is to consider the more standard definition of $e$, which is $\lim_{n\to\infty}(1 + \frac{1}{n})^n$. Therefore, $e^a$ can be written as $\lim_{n\to\infty}(1 + \frac{1}{n})^{an}$. Using the binomial theorem, the expression expands to $$\lim_{n\to\infty}(1 + \frac{an}{n} + \frac{an(an - 1)}{2n^2}+ \frac{an(an-1)(an-2)}{6n^3} + \ldots)$$ The lesser powers in the numerators drop out, so the expression becomes $$1 + a + \frac{a^2}{2} + \frac{a^3}{6} + \ldots$$which is $\sum_{i=0}^{\infty}\frac{a^i}{i!}$ in sum notation.