Let $\mu$ be a probability measure $\mathbb{R}^n$ (on the Borel or Lebesgue $\sigma$-algebra, I do not really care) which is supported on $\mathbb{S}^{n-1}$. (You can just think on a measure on the sphere itself).
Suppose that for some unit vector $v \in \mathbb{S}^{n-1}$, it holds that
$$ v= \int_{\mathbb{S}^{n-1}} x \, d\mu(x)$$ (That is $v$ is a "continuous" convex combination of the points of the sphere).
How to prove that $\mu = \delta_v$?
(I know this holds for finite combinations, and I am not sure how to generalize to the continuous case)
Suppose $\mu$ is a Borel probability measure supported on $S=S^{n-1}$ satisfying the stated equality. We want to show that $\mu=\delta_\nu$ which is equivalent to $\mu(S\setminus\{\nu\})=0$. Now, $$S\setminus \{\nu\} = \bigcup_{k\geq 1} \left(S \setminus B\left(\nu,\frac1{n}\right)\right)$$ is a countable union of compact sets. So by $\sigma$-additivity it suffices to show that $\mu(K)=0$ for every compact set $K\subset S^{n-1}\setminus\{\nu\}$. So suppose this is not the case and that $r:=\mu(K)>0$ for some such $K$.
Since $K$ is compact and disjoint from $\nu$: $$\sup_{x\in K}\nu\cdot x = \max_{x\in K}\nu\cdot x=:k<1$$ And then $$1=\nu\cdot \nu =\int_S \nu\cdot x d\mu = \int_K \nu\cdot x d\mu + \int_{S-K} \nu\cdot x d\mu \leq k r + (1-r) 1 <1 $$ Contradiction.