I've been looking at the principal curvature lines of many surfaces and I realized that the principal curvature lines of the sphere intersect
, whereas the principal curvature lines of other surfaces don't.
Also, this is not the case for all closed surfaces, for example, the one holed torus principal curvature lines don't intersect. However, these lines for the two-holed torus do.

I have also been wondering if this has any relation with the global or local parametrization of these surfaces, for example, there is a different "type" of discontinuity in the parametrization of the sphere at the poles.
Be careful: On the sphere, any curve whatsoever is a line of curvature. The phenomenon you're noticing on the two-holed torus is that these intersections can occur only at umbilic points. Otherwise, there are precisely two principal directions at each point and there can be no such intersections. Of course, every point on the sphere is an umbilic and you can get as many intersections as you want by taking crazy curves (which will be lines of curvature). (The particular picture you're drawing with Mathematica is based on the spherical coordinates parametrization, so it's just the singularity of the coordinate system that's being reflected in this picture.)