Let $A$ be an associative algebra over a field $k$, and let $L/k$ be any field extension.
Assume that $A \otimes_k L$ is a field (not necessarily a finite extension of $L$ !). Can we deduce that $A$ is a field?
I know that $A$ is a (commutative, unital) integral domain, since $A \cong A \otimes_k k$ embeds in $A \otimes_k L$. But how to go further?
Maybe if $L/k$ is Galois, we can use $A \cong (A \otimes_k L)^{Gal(L/k)}$, after checking that this is indeed a $k$-algebra isomorphism ?
Yes, $A$ is a field. We don't need to assume that the field extension is Galois or finite.
Proof. Faithfulness can be proven pretty explicitly by choosing bases if necessary. As for conservativity, if $V$ and $W$ are finite-dimensional we can argue using determinants; in general we can use the fact that faithful functors reflect epimorphisms and monomorphisms, so if $T_L$ is an isomorphism then $T$ is both an epimorphism and a monomorphism and hence an isomorphism (note that we really need to be working in a nice category like an abelian category here; this is false in general categories). $\Box$
Now we can argue as follows. An element $a \in A$ is invertible iff left multiplication $A \xrightarrow{a} A$ is an isomorphism (of $k$-modules). If $a \in A$ is nonzero then $a_L \in A_L$ is nonzero by faithfulness, and hence invertible since $A_L$ is a field by hypothesis. By conservativity, $a$ is invertible. Hence $A$ is a field.
This argument applies more generally to any faithfully flat ring homomorphism $R \to S$ replacing $k \to L$: these are also faithful and conservative, and so also don't make anything invertible that wasn't invertible already.