Suppose that $Z$ (a scalar) is independent with $X=(X_1,\ldots,X_n)$, $n>1$. Then, $Z$ is independent with $X_1,\ldots,X_n$ because each of the latter is a function of $X$.
I suspect the reverse direction: $Z$ being independent with $X_1,\ldots,X_n$ implying $Z$ being independent with $X$ is not true. Most likely because we would need some info about the joint distribution of $X_1,\ldots,X_n$. But I can't think of a counter example. So could you please provide one as well as some intuition on how you arrive at it?
Yes, in general the converse is not correct. The reason is, essentially, that pairwise independence does not imply independence.
Example Let $\Omega := \{0,1\}^2$ and $\mathbb{P}(\{\omega\}) := 1/4$, $\omega \in \Omega$. For $\omega = (\omega_1,\omega_2)$ define
$$X_1(\omega) := \omega_1 \qquad X_2(\omega) := \omega_2 \qquad Z(\omega) :=1_{\{\omega_1=\omega_2\}}.$$
Then it is not difficult to see that
$$ \mathbb{P}(X_1 = i, Z=j) = \frac{1}{4} = \mathbb{P}(X_1=i) \mathbb{P}(Z=j)$$
for any $i,j \in \{0,1\}$ which shows that $X_1$ and $Z$ are independent. In an analogous way we find that $X_2$ and $Z$ are independent. However, $Z$ and $X:=(X_1,X_2)$ are not independent since
$$\mathbb{P}(Z=1, X=(1,1)) = \frac{1}{4} \neq \frac{1}{8} = \mathbb{P}(Z=1) \mathbb{P}(X=(1,1)).$$