Consider the following block matrix
$$M = \begin{bmatrix} I+A & -I\\ -I & I+A \end{bmatrix}$$
in which $I$ represents the identity matrix of size $n$ and $A$ is a symmetric and positive semidefinite (PSD) matrix. Can I say $M$ is PSD?
Since $I+A$ is positive definite, I can apply the determinant formula for block-matrices which gives $1 + \mbox{eig}(A)$ as eigenvalues of $M$. What are the other eigenvalues? Are they smaller than $1 + \max(\mbox{eig}(A))$?
Claim: $M$ is positive semi-definite.
To realize this, look at the question number $3.2$ from chapter $3$ of the following book by Dr. Vern Paulsen :
https://books.google.ca/books/about/Completely_Bounded_Maps_and_Operator_Alg.html?id=VtSFHDABxMIC&hl=en
For quick reference, let me write the question: Suppose $P,Q,S$ are operators on some Hilbert space $\mathcal{H}$ with $P,Q$ positive semi-definite, then the matrix $$ \begin{bmatrix} P & S\\ S^* & Q \end{bmatrix} $$ will be positive semi-definite if and only if $|\langle{Sx},{y}\rangle|^2\leq \langle{Py},{y}\rangle \langle{Qx},{x}\rangle$ for every $x,y\in \mathcal{H}$.
Notice that in your question $P=Q=I+A$ which is psd and $S=S^*=-I$. Use Cauchy-Schwartz inequality to deduce that $|\langle{-x},{y}\rangle|^2\leq \langle{(I+A)y},{y}\rangle \langle{(I+A)x},{x}\rangle$ for every $x,y\in \mathbb{C}^n$. This proves the claim.