WLOG, let $a$ be the side of a triangle inscribed in a unit circle and $A$ be the opposite angle. Experimental data shows that there is a constant $C \approx 3.6394$ such that $aA \le C$.
Question: What is the maximum value of $aA$?
Progress: Trivially, $\max \left (aA\right) \ge \pi$. This follows from the case when the triangle is a right triangle in a semi-circle so that $a = 2$ and $A = \frac{\pi}{2}$. A slightly less trivial bound is $\max \left (aA\right) \ge \left( \frac{2\pi}{\sqrt{3}}\right) \approx 3.6276$ which very close to the experimentally observed maxima. This corresponds to the case when we have a triangle whose angles are $\left(\frac{2\pi}{3}, \frac{\pi}{6}, \frac{\pi}{6}\right)$.

Let us take a Point $D$ on the Unit Circle , such that the Diametrically Opposite Point is $A$.
Let a Point $P$ move on $DA$ , whereby we get the triangle with Altitude $AP$.
When Angle at $A$ is $a$ , then the angle at the Center will be $2a$ , hence the base will be $2\sin(a)$.
The value we want to maximize is $P = 2a \sin(a)$
$dP/da = 2 \sin(a) + 2a \cos(a)$
This has a Zero at $\tan(a) = -a$ which gives a value a ≈ 2.02875783811043... (according to wolfram)
That gives $P = 3.639411482319306092413915357584$
This Maximum value is the Constant $C$ we want.